Ultrafast-charging and long cycle-life anode materials of TiO<inf>2</inf>-bronze/nitrogen-doped graphene nanocomposites for high-performance lithium-ion batteries

Abstract

© The Royal Society of Chemistry. Emerging technologies demand a new generation of lithium-ion batteries that are high in power density, fast-charging, safe to use, and have long cycle lives. This work reports charging rates and specific capacities of TiO2(B)/N-doped graphene (TNG) composites. The TNG composites were prepared by the hydrothermal method in various reaction times (3, 6, 9, 12, and 24 h), while the N-doped graphene was synthesized using the modified Hummer's method followed by a heat-treatment process. The different morphologies of TiO2 dispersed on the N-doped graphene sheet were confirmed as anatase-nanoparticles (3, 6 h), TiO2(B)-nanotubes (9 h), and TiO2(B)-nanorods (12, 24 h) by XRD, TEM, and EELS. In electrochemical studies, the best battery performance was obtained with the nanorods TiO2(B)/N-doped graphene (TNG-24h) electrode, with a relatively high specific capacity of 500 mA h g-1 at 1C (539.5 mA g-1). In long-term cycling, excellent stability was observed. The capacity retention of 150 mA h g-1 was observed after 7000 cycles, at an ultrahigh current of 50C (27.0 A g-1). The synthesized composites have the potential for fast-charging and have high stability, showing potential as an anode material in advanced power batteries for next-generation applications. This journal is