Please use this identifier to cite or link to this item: http://cmuir.cmu.ac.th/jspui/handle/6653943832/55481
Title: Kagome-type isostructural 3D-transition metal fluorosulfates with spin 3/2 and 1: Synthesis, structure and characterization
Authors: Subba R. Marri
Jitendra Kumar
Kitt Panyarat
Satoshi Horike
J. N. Behera
Keywords: Chemistry
Issue Date: 1-Jan-2016
Abstract: © 2016 The Royal Society of Chemistry. Two isostructural transition metal fluorosulfates based on Co and Ni metal ions with the molecular composition of [H3O][M(SO4)F] (where M = Co(II)for 1 and Ni(II)for 2) were synthesized under solvothermal conditions and structurally characterized by single crystal X-ray analysis. The materials were further characterized by complementary techniques like TGA, FTIR and PXRD. The 3D-crystal lattice consists of a kagome-type entity where sulfate groups replaced one of the metal nodes when compared with true kagome structures. Magnetic studies of the complexes were also performed which showed that the interactions at the metal center are antiferromagnetic in nature. The proton conductivity increases with the increase in humidity and was found to be 7.9 × 10-6S cm-1for 2 at RH = 98%.
URI: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84994518742&origin=inward
http://cmuir.cmu.ac.th/jspui/handle/6653943832/55481
ISSN: 14779234
14779226
Appears in Collections:CMUL: Journal Articles

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