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dc.contributor.authorThanphat Thaimaen_US
dc.contributor.authorArife Yazicien_US
dc.contributor.authorChiramet Auranwiwaten_US
dc.contributor.authorAnthony C. Willisen_US
dc.contributor.authorUta Willeen_US
dc.contributor.authorThunwadee Limtharakulen_US
dc.contributor.authorStephen G. Pyneen_US
dc.description.abstract© 2021 The Royal Society of Chemistry. The reactions of α,β-unsaturated N-acyliminium ions, generated in situ from 4(S)-O-substitutedhydroxy-5-hydroxy-5-vinyl-N-alkylpyrrolidin-2-ones, with allylsilanes and indoles leading to the formation of spirocyclic heterocycles, are reported. Six single crystal X-ray structures and extensive 2D NMR experiments confirmed the structures and stereochemistries of these products. In addition, computational studies provided mechanistic insights and an understanding of the stereochemical outcomes of these reactions.en_US
dc.subjectBiochemistry, Genetics and Molecular Biologyen_US
dc.titleSynthesis of spirocyclic heterocycles from α,β-unsaturated N -acyliminium ionsen_US
article.title.sourcetitleOrganic and Biomolecular Chemistryen_US
article.volume19en_US Molecular Science and Biotechnology Instituteen_US of Wollongongen_US Australian National Universityen_US Mai Universityen_US
Appears in Collections:CMUL: Journal Articles

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