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dc.contributor.authorNatthaya Meundaengen_US
dc.contributor.authorApinpus Rujiwatraen_US
dc.contributor.authorTimothy J. Prioren_US
dc.description.abstract© 2016 Elsevier Inc. We have successfully prepared crystals of thiazole-5-carboxylic acid (5-Htza) (L) and three new thiazole-5-carboxylate-based Cu2+coordination polymers with different dimensionality, namely, 1D [Cu2(5-tza)2(1,10-phenanthroline)2(NO3)2] (1), 2D [Cu(5-tza)2(MeOH)2] (2), and 3D [Cu(5-tza)2]·H2O (3). These have been characterized by single crystal X-ray diffraction and thermogravimetry. Interestingly, the 2D network structure of 2 can directly transform into the 3D framework of 3 upon removal of methanol molecules at room temperature. 2 can also undergo structural transformation to produce the same 2D network present in the known [Cu(5-tza)2]·1.5H2O upon heat treatment for 2 h. This 2D network can adsorb water and convert to 3 upon exposure to air.en_US
dc.subjectMaterials Scienceen_US
dc.subjectPhysics and Astronomyen_US
dc.titleCopper coordination polymers constructed from thiazole-5-carboxylic acid: Synthesis, crystal structures, and structural transformationen_US
article.title.sourcetitleJournal of Solid State Chemistryen_US
article.volume245en_US Mai Universityen_US of Hullen_US
Appears in Collections:CMUL: Journal Articles

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