Please use this identifier to cite or link to this item: http://cmuir.cmu.ac.th/jspui/handle/6653943832/6358
Title: Characterization of copper sulfide nanostructured spheres and nanotubes synthesized by microwave-assisted solvothermal method
Authors: Thongtem T.
Phuruangrat A.
Thongtem S.
Issue Date: 2010
Abstract: Copper sulfide nanostructured spheres and nanotubes were successfully synthesized, using a microwave-assisted solvothermal method, by the decomposition of [Cu(CH3CSNH2)2]Cl2 complexes, formed by the reaction of CuCl2·2H2O and CH3CSNH2 in ethylene glycol at different pH values, and identified by CHNS/O and FTIR analyses. The decrease in bonding energy of N-H revealed the coordination of copper ions and thioacetamide molecules. It was specified that nitrogen atoms of thioacetamide molecules were used to form Cu-thioacetamide complexes. XRD, SEM, TEM and SAED analyses show that the products were hexagonal CuS spheres in an extremely low pH solution, and hexagonal CuS nanotubes at a pH 13. Their Raman spectra show sharp peaks at 473 cm- 1, identified as the S-S stretching mode of S2 ions at the 4e sites. © 2009 Elsevier B.V. All rights reserved.
URI: http://www.scopus.com/inward/record.url?eid=2-s2.0-70449536385&partnerID=40&md5=642a38104e0130abdff6597cb1520e31
http://cmuir.cmu.ac.th/handle/6653943832/6358
ISSN: 0167577X
Appears in Collections:SCIENCE: Journal Articles

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