Please use this identifier to cite or link to this item: http://cmuir.cmu.ac.th/jspui/handle/6653943832/5922
Title: (1-Butyl-1,4-diaza-bicyclo-[2.2.2]octon-1-ium-N 4) trichloridocobalt(II)
Authors: Luachan S.
Yotnoi B.
Prior T.J.
Rujiwatra A.
Issue Date: 2009
Abstract: The title compound, [Co(C10H21N2)Cl3], was obtained as the by-product of the attempted synthesis of a cobalt sulfate framework using 1,4-diaza-bicyclo-[2.2.2]octane as an organic template. The asymmetric unit comprises two distinct mol-ecules, and in each, the cobalt(II) ions are tetra-hedrally coordinated by three chloride anions and one 1-butyl-diaza-bicyclo-[2.2.2]octan-1-ium cation. The organic ligands are generated in situ, and exhibit two forms differentiated by the eclipsed and staggered conformations of the butyl groups. These mol-ecules inter-act by way of C - H⋯Cl hydrogen bonds, forming a three-dimensional hydrogen-bonding array.
URI: http://www.scopus.com/inward/record.url?eid=2-s2.0-62149115690&partnerID=40&md5=bf6a2abc4fef2b40b40e978b23d72b08
http://cmuir.cmu.ac.th/handle/6653943832/5922
ISSN: 16005368
Appears in Collections:SCIENCE: Journal Articles

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