New vegetable oils with different fatty acids on natural rubber composite properties

Abstract

Owing to the toxicity of polycyclic aromatic (PCA) oils, much attention has been paid to the replacement of PCA oils by other nontoxic oils. This paper reports comparative study of the effects of new vegetable oils, i.e., Moringa oil (MO) and Niger oil (NO), on rheological, physical and dynamic properties of silica-filled natural rubber composite (NRC), in comparison with petroleum-based naphthenic oil (NTO). The results reveal that MO and NO exhibit higher thermal stability and better processability than NTO. Cure characteristics of the rubber compounds are not significantly affected by the oil type. It is also found that the NRCs containing MO or NO have better tensile strength and lower dynamic energy loss than the NRCs containing NTO. This may be because both MO and NO improve filler dispersion to a greater extent than NTO as supported by storage modulus and scanning electron microscopy results. Consequently, the present study suggests that MO and NO could be used as the alternative non-toxic oils for NRC without any loss of the properties evaluated.