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Title: | Photoluminescent ionic solids of s-bridged gold(i)-gallium(iii) and gold(i)-indium(iii) hexanuclear complexes |
Authors: | Takuma Itai Naoto Kuwamura Tatsuhiro Kojima Nobuto Yoshinari Apinpus Rujiwatra Takumi Konno |
Authors: | Takuma Itai Naoto Kuwamura Tatsuhiro Kojima Nobuto Yoshinari Apinpus Rujiwatra Takumi Konno |
Keywords: | Chemistry |
Issue Date: | 1-Aug-2021 |
Abstract: | Reactions of [Au2(dppe)(D-Hpen)2] (dppe = 1,2-bis(diphenylphosphino) ethane, D-H2pen = D-penicillamine) with M(NO3)3 (M = GaIII, InIII) afforded charge-separation-type ionic solids, [Au4M2(dppe)2(D-pen)4](NO3)2, in which each M center is surrounded by two D-pen ligands to form an N2O2S2 octahedral geometry. The ionic solids exhibited blue emission originating from the LLCT excited state in the solid state. |
URI: | https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85114797587&origin=inward http://cmuir.cmu.ac.th/jspui/handle/6653943832/76101 |
ISSN: | 13480634 00092673 |
Appears in Collections: | CMUL: Journal Articles |
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