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Title: Unsaturated Mn(II)-Centered [Mn(BDC)]<inf>n</inf> Metal-Organic Framework with Strong Water Binding Ability and Its Potential for Dehydration of an Ethanol/Water Mixture
Authors: Kanyaporn Adpakpang
Warat Pratanpornlerd
Panyapat Ponchai
Wararat Tranganphaibul
Sutarat Thongratkaew
Kajornsak Faungnawakij
Satoshi Horike
Theeranun Siritanon
Apinpus Rujiwatra
Makoto Ogawa
Sareeya Bureekaew
Keywords: Chemistry
Issue Date: 5-Nov-2018
Abstract: Copyright © 2018 American Chemical Society. An unsaturated Mn(II)-centered metal-organic framework was synthesized. The presence of an unsaturated Mn(II) center, together with a guest-responsive structural changing feature, plays a crucial role for strong binding with water, leading to its potential application for water/ethanol separation. In addition, the present framework is thermally stable up to 400 °C, which is beneficial for the regeneration process after adsorption.
ISSN: 1520510X
Appears in Collections:CMUL: Journal Articles

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