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dc.contributor.authorBunlawee Yotnoien_US
dc.contributor.authorNatthaya Meundaengen_US
dc.contributor.authorWatcharee Funfuenhaen_US
dc.contributor.authorMookda Pattarawarapanen_US
dc.contributor.authorTimothy J. Prioren_US
dc.contributor.authorApinpus Rujiwatraen_US
dc.description.abstract© 2015 Taylor and Francis. A series of new lanthanide coordination polymers has been synthesized and structurally characterized; [Ln4(TTHA)2(pzac)(H3O)2(H2O)]·5H2O (Ln = Pr (1a) and Nd (1b)), [Sm8(TTHA)4(pzac)0.5(H3O)(H2O)7.5]·4H2O (2), [Ln4(HTTHA)2(SO4)(H2O)4]·5H2O (Ln = Pr (3a) and Nd (3b)), where H6TTHA = 1,3,5-triazine-2,4,6-triamine hexaacetic acid, and H2pzac = 2,5-dioxo-piperazine-1,4-diacetic acid. The compounds feature 3-D frameworks comprising the deprotonated H6TTHA as the primary ligand and either the in situ generated pzac2-or sulfate as the secondary ligands. The influence of the deprotonated H6TTHA in directing the framework structures through preferential coordination modes and molecular conformation is described. The effect of the secondary ligands in increasing the compactness of the frameworks and in the alternation of the framework topologies based on the four-connected pts type is described.en_US
dc.subjectMaterials Scienceen_US
dc.titleInfluence of secondary ligand on structures and topologies of lanthanide coordination polymers with 1,3,5-triazine-2,4,6-triamine hexaacetic aciden_US
article.title.sourcetitleJournal of Coordination Chemistryen_US
article.volume68en_US Mai Universityen_US of Hullen_US
Appears in Collections:CMUL: Journal Articles

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