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|Title:||Facile and efficient synthesis of C<inf>2</inf>-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation|
|Keywords:||Biochemistry, Genetics and Molecular Biology|
Pharmacology, Toxicology and Pharmaceutics
|Abstract:||© 2014 Elsevier Ltd. All rights reserved. A rapid and efficient method for preparation of C2-symmetrical 1,3,5-triazine polycarboxylate ligands was developed. The reactions included either selective mono- or di-substitution of 2,4,6-trichloro-1,3,5-triazine with various nucleophiles containing carboxyl group(s), followed by nucleophilic displacement of the remained chloride(s) in aqueous media under microwave irradiation. Novel C2-symmetrical tripodal ligands were afforded in good yields and purities under short reaction time with simple work-up, which are potentially useful as structural directing units in metal-organic frameworks.|
|Appears in Collections:||CMUL: Journal Articles|
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