Please use this identifier to cite or link to this item: http://cmuir.cmu.ac.th/jspui/handle/6653943832/53182
Title: Facile and efficient synthesis of C<inf>2</inf>-symmetrical 1,3,5-triazine polycarboxylate ligands under microwave irradiation
Authors: Watcharee Funfuenha
Wong Phakhodee
Mookda Pattarawarapan
Keywords: Biochemistry, Genetics and Molecular Biology
Chemistry
Pharmacology, Toxicology and Pharmaceutics
Issue Date: 2-Sep-2014
Abstract: © 2014 Elsevier Ltd. All rights reserved. A rapid and efficient method for preparation of C2-symmetrical 1,3,5-triazine polycarboxylate ligands was developed. The reactions included either selective mono- or di-substitution of 2,4,6-trichloro-1,3,5-triazine with various nucleophiles containing carboxyl group(s), followed by nucleophilic displacement of the remained chloride(s) in aqueous media under microwave irradiation. Novel C2-symmetrical tripodal ligands were afforded in good yields and purities under short reaction time with simple work-up, which are potentially useful as structural directing units in metal-organic frameworks.
URI: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84949124339&origin=inward
http://cmuir.cmu.ac.th/jspui/handle/6653943832/53182
ISSN: 14645416
00404020
Appears in Collections:CMUL: Journal Articles

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